Standard Test Method for Hydroxyl Groups Using Reaction with p-Toluenesulfonyl Isocyanate (TSI) and Potentiometric Titration with Tetrabutylammonium Hydroxide

Standard [CURRENT]

ASTM E 1899:2023

Standard Test Method for Hydroxyl Groups Using Reaction with p-Toluenesulfonyl Isocyanate (TSI) and Potentiometric Titration with Tetrabutylammonium Hydroxide

Publication date
2023
Original language
English
Pages
6

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Publication date
2023
Original language
English
Pages
6
DOI
https://dx.doi.org/10.1520/E1899-23

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Short description

1.1 This test method covers the determination of hydroxyl groups attached to primary and secondary carbon atoms in aliphatic and cyclic compounds and phenols from 0.5 to 367 hydroxyl number. It is not suitable for determination of hydroxyl groups attached to tertiary carbon atoms. This test method is applicable to polyacetals, temperature sensitive materials, high solids polymer polyols, and rigid polyols. Other available test methods listed in Note 1 are not suitable for many of the sample types listed above. 1.1.1 This test method is currently recommended for neutral refined products. Successful application has been made, however, to some in-process samples that contain an excess of acidic species. Proper validation must be performed, of course, to show that the acidic species either does not interfere, or that the acidic species interference has been obviated. Note 1: Other methods for determination of hydroxyl groups are given in Test Methods D817 , D871 , D4252 , D4273 , D4274 , E222 , E326 , and E335.

ICS

71.040.40

DOI

https://dx.doi.org/10.1520/E1899-23
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