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This Technical Specification specifies the procedure for the sampling of individual volatile organic compounds (VOCs) in waste gas as well as sample preparation and analysis. The source of waste gas can be, for example, solvent-using processes. Sampling occurs by adsorption on sorbents, preparation by solvent extraction or thermodesorption and analysis by gas chromatography. Examples of individual organic compounds are given in relevant industry sector BAT reference documents (BREFs). This Technical Specification is applicable in conjunction with the Industrial Emission Directive (IED) and associated supporting documents. It is relevant to operators of IED-related systems, surveillance authorities and measurement institutes.